Is Matter Around Us Pure

Which of the following are physical changes?
(i) Melting of iron metal
(ii) Rusting of iron
(iii) Bending of an iron rod
(iv) Drawing a wire of iron metal
(a) (i), (ii) and (iii)
(b) (i), (ii) and (iv)
(c) (i), (iii) and (iv)
(d) (ii), (iii) and (iv)